Tetrakis(triphenylarsine)copper(I) hexafluoridophosphate
نویسندگان
چکیده
In the crystal structure of the title compound, [Cu(C(18)H(15)As)(4)]PF(6), the Cu atom is coordinated by four As atoms of triphenyl-arsine ligands in a tetra-hedral geometry. The complex cation is located on a crystallographic threefold axis. Both PF(6) (-) anions are located on special positions of site symmetry . The Cu-As bond of the independent arsine ligand is shorter than the Cu-As bonds of the three symmetry-related arsine ligands.
منابع مشابه
Tetrakis[μ-1,3-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2 N:N′]trisilver(I) tris(hexafluoridophosphate)
In the title compound, [Ag(3)(C(12)H(12)N(2)O(2))(4)](PF(6))(3), one Ag(I) ion, lying on a twofold rotation axis, is coordinated by four N atoms from four 1,3-bis-(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted tetra-hedral geometry and the other Ag(I) ion is coordinated by two N atoms from two L ligands in a bent arrangement [N-Ag-N = 169.03 (17)°]. Two L ligands adopt a syn co...
متن کاملTetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate
In the title compound, [Li(CH(3)CN)(4)]PF(6)·CH(3)CN, the asymmetric unit consists of three independent tetra-hedral [Li(CH(3)CN)(4)](+) cations, three uncoordinated PF(6) (-) anions and three uncoordinated CH(3)CN solvent mol-ecules. The three anions are disordered over two sites through a rotation along one of the F-P-F axes. The relative occupancies of the two sites for the F atoms are 0.643...
متن کاملA new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-μ3-iodido-tetrakis[(benzyldimethylamine-κN)copper(I)]
The title compound, [Cu(4)I(4)(C(9)H(13)N)(4)], has a distorted cubane-like [Cu(4)I(4)] core structure. Each Cu(I) atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyl-dimethyl-amine ligand. Each I atom acts as a μ(3)-ligand, linking three Cu(I) atoms. The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) Å, while the Cu-N bond distances vary between 2.107 (3...
متن کاملAn ionic organic–inorganic hybrid: tetrakis[bis(1,10-phenanthroline)copper(I)] dodecatungstophosphate(V). Corrigendum
The chemical name in the title of the paper by Meng, Liu & Chen [Acta Cryst. (2008), E64, m106] is corrected.[This corrects the article DOI: 10.1107/S1600536807062903.].
متن کاملThe mixed-valent copper thiolate complex hexakis{μ3-2-[(1,3-dimethylimidazolidene)amino]benzenethiolato}dicopper(II)tetracopper(I) bis(hexafluoridophosphate) acetonitrile disolvate dichloromethane disolvate
The mol-ecular structure of the title compound, [Cu4(I)Cu2(II)(C11H14N3S)6](PF6)2·2CH3CN·2CH2Cl2, shows a mixed-valent copper(I/II) thiol-ate complex with a distorted tetra-hedral coordination of the Cu(I) and Cu(II) cations by one guanidine N atom and three S atoms each. Characteristic features of the Cu6S6 skeleton are a total of six chemically identical μ3-thiol-ate bridges and almost planar...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007